基于TVR的腐蚀油气管道失效概率及安全寿命研究

为避免因腐蚀导致油气管道失效，针对因管道特性和腐蚀尺寸的不确定性使得管道剩余强度成为概率模型的特点，建立了腐蚀管道强度损失随机模型；借助可靠性理论，通过分析管道腐蚀进程的时变性特点，将管道系统由损伤积累和抗力衰减导致的剩余强度随机化；提出基于穿越率的腐蚀油气管道失效评定及安全寿命预测方法。研究结果表明:腐蚀速率和运行压力对管道失效概率及安全寿命影响显著,管道尺寸影响适中，而相关系数和拉伸强度影响较小；若腐蚀速率Va=0.2 mm/a，VL=10 mm/a或局部腐蚀缺陷半径达到管道壁厚的0.5倍时，建议作为重点风险段监测并检修。所建方法是对腐蚀油气管道运营监控和风险评估的有益补充。     

高瓦斯工作面隅角柔性气囊安全封堵研究

为解决高瓦斯工作面隅角封堵工人劳动强度大、效率低,封堵效果不佳易造成隅角瓦斯浓度超限等安全问题,研发设计了矿用阻燃内外胆组合结构的轻型柔性隅角封堵气囊,并相应提出了单体液压支柱配合轻型柔性气囊的隅角封堵新方法。通过实验室测试实验和现场工业性试验表明:选用PVC材料和双抗涂覆布材料的气囊质量小、轻便实用,大幅降低了工人的劳动强度,提高了工作效率,减小了传统封堵方式编织袋装碎煤造成的遗煤浪费;该气囊可适应大变形(变形率可达42.5%)、耐冲击(2×104J的冲击能量不破坏),抗撕扯能力强,且具有阻燃特性,重复使用率高,大大节约了隅角封堵的成本;使用气囊封堵后,采空区内瓦斯浓度显著增大,说明气囊封堵的密闭性增加,安全封堵效果十分明显。     

挥发性有机污染物排放控制标准制订中的关键技术问题研究

研究分析了挥发性有机污染物排放标准制订中4个关键技术问题:污染因子选择、控制指标确定、限值的确定以及技术管理措施.结果表明,应根据毒性和光化学反应性选择污染因子;确定控制指标应既考虑有组织控制指标,又考虑无组织的控制指标;确定排放限值应明确是基于控制技术还是基于健康风险;同时制定技术管理措施以通过源头和过程控制挥发性有机污染物排放.     

四氯丙烯对稀有鮈鲫的急性毒性及安全浓度评价

采用半静态试验方式测试了四氯丙烯对稀有鮈鲫(Gobiocypris rarus)的急性毒性,试验浓度分别设定为0.25 mg·L~(-1)、0.30mg·L~(-1)、0.36 mg·L~(-1)、0.42 mg·L~(-1)、0.50 mg·L~(-1)和0.60 mg·L~(-1),同时进行空白对照(试验用水)和分散剂对照(体积分数为0.006%的吐温-80水溶液)试验。采用气相色谱法对试验溶液进行浓度分析,实测浓度分别为0.19 mg·L~(-1)、0.25 mg·L~(-1)、0.34 mg·L~(-1)、0.40 mg·L~(-1)、0.51 mg·L~(-1)和0.64 mg·L~(-1),试验结果以实测浓度表示和统计。结果表明:四氯丙烯致稀有鮈鲫无死亡发生(EC0)的最高浓度为0.25 mg·L~(-1),导致稀有鮈鲫100%死亡(EC100)的最低浓度为0.51 mg·L~(-1)。根据实测浓度,用SPSS(17.0)概率单位法求得四氯丙烯对稀有鮈鲫的半数致死浓度96 h-LC50为0.347 mg·L~(-1),95%置信区间为0.328 mg·L~(-1)~0.361 mg·L~(-1)。     

Application of CFD on the sensitivity analyses of some parameters of the modified Hartmann tube

The aim of this work is to determine the influence of operating parameters such as the dispersion pressure, the ignition delay and height on the dust flammability. A Computational Fluid Dynamics (CFD) simulation, based on an Euler–Lagrange approach, was developed with Ansys Fluent™ and validated experimentally. Such analysis will facilitate the choice of the most conservative conditions for a flammability test. This paper is focused on a case study performed on wheat starch with the modified Hartmann tube. The dispersion process of the powder was studied with granulometric analyses performed in situ and high speed videos. Tests were performed with injections at gas pressure ranging from 3 to 6 bars and the evolution of the particle size distribution (PSD) was recorded at different ignition heights (5, 10 and 15 cm over the dispersion nozzle). The observations highlighted the presence of agglomeration/deagglomeration processes and dust segregation. Besides, a CFD simulation analysis was aimed at evaluating the impact of a set of parameters on the PSD and the local turbulence, which are closely linked to some flammability parameters. For this computational analysis, the CFD simulation was coupled with a collision treatment based on a Discrete Element Method (DEM) in order to consider the cohesive behavior of the combustible dust. Thus the results suggest performing the injection of the gases at approximately 5 bars for the flammability tests of wheat starch in order to obtain the finest PSD at a given ignition height. It is also shown that the finest PSD are obtained at 5 cm over the dispersion nozzle. However, the local instabilities and turbulence levels are so high during the first stages of the dispersion that the flame growth can be disturbed for short ignition delays. Moreover, the stabilization of the bulk of the dust cloud requires longer periods of time when the ignition sources are located at 15 cm. As a result, the recommended height to perform a flammability test is 10 cm in this case. Finally, this study proposes some tools that might improve the procedure of dust flammability testing.     

Determination of explosion limits – Criterion for ignition under non-atmospheric conditions

Many industrial processes are run at non-atmospheric conditions (elevated temperatures and pressures, other oxidizers than air). To judge whether and if yes to what extent explosive gas(vapor)/air mixtures will occur or may be generated during malfunction it is necessary to know the safety characteristic data at the respective conditions. Safety characteristic data like explosion limits, are depending on pressure, temperature and the oxidizer. Most of the determination methods are standardized for ambient conditions. In order to obtain determination methods for non-atmospheric conditions, particularly for higher initial pressures, reliable ignition criteria were investigated. Ignition tests at the explosion limits were carried out for mixtures of methane, propane, n-butane, n-hexane, hydrogen, ammonia and acetone in air at initial pressures up to 20 bar. The tests have been evaluated according to different ignition criteria: visual flame propagation, temperature and pressure rising. It could be shown that flame propagation and occasionally self-sustained combustion for several seconds occurred together with remarkable temperature rise, although the pressure rise was below 3%. The results showed that the combination of a pressure rise criterion of 2% and a temperature rise criterion of 100 K seems to be a suitable ignition criterion for the determination of explosion limits and limiting oxidizer concentration at higher initial pressures and elevated temperatures. The tests were carried out within the framework of a R&D project founded by the German Ministry of Economics and Technology.     

外浮顶罐充氮管网设计及有效性试验验证

为了预防外浮顶罐密封圈雷击火灾,提出在密封圈内充入氮气的保护方法.将安全含氧量作为充氮的惰化目标,对外浮顶罐充氮管网进行设计,并通过试验来验证充氮管网的有效性.试验得到了充氮流量、进出气孔数量及管径与有效充氮时间的关系.若以142 m3/h的流量对容量为10×104 m3的外浮顶罐密封圈内充氮,则46.5 min内可以达到充氮惰化目标.雷电预警时间为60 ～ 90 min的条件下,充氮时间小于预警时间,表明所设计的管网是有效的.     

区块链技术在安全生产信息化建设中的应用

为了促进安全生产信息化平台在数据方面进行分析以及整合,基于区块链本身的匿名性、去中心化、安全性、开放性以及独立性等优势,提出将区块链技术应用于安全生产信息化建设,研究表明,区块链技术的应用将能够为企业针对生产安全状态进行有效监督提供最大的帮助,最大限度的实现资源共享,为企业监督、政府部门监管提供便利条件,各企业之间就安全问题进行交流沟通,安全评价服务机构针对各企业安全生产存在的问题提供更有针对性的服务,同时对于提升服务效率以及服务质量有着重要现实意义。     

Experimental investigation of the lower flammability limit of volatile liquid fuel-aluminum powder mixtures in air

Aluminum powder was always chosen as an additive to improve the explosive performance. In this work, experiments were performed to investigate the lower flammability limit (LFL) of volatile liquid fuel-aluminum powder mixtures using a 20 L closed spherical stainless steel vessel at a temperature of 20 °C (293 K) and 40 °C (313 K). The volatile liquid fuels tested in the work were diethyl ether (DEE), epoxypropane (PO), n-pentane and n-hexane. DEE, PO and n-pentane are in the liquid phase at room temperature and can easily transition to the gas phase at 40 °C (313 K). Through a series of experiments carried out, it was found that the change in phase would affect the interaction between the components. Aluminum powder always has an inhibitory effect on the flammability of the mixtures when it is mixed with gas-phase fuels. The inhibition effect was most obvious when the aluminum powder concentration reached 200 g/m³. While the interaction between aluminum powder and liquid-phase volatile fuels was promotion and was influenced by the component proportion and the type of the volatile fuels.     

“T”型地铁换乘站多点火灾工况下综合火灾危险性研究

为探究大型地铁站多线路火灾场景中的综合危险性，采用火灾动力学软件FDS构建“T”型换乘站全尺寸模型，对不同火源位置、不同火源功率以及是否开启地铁排烟风机等12组工况进行数值模拟；采用性能化方法确定可用疏散时间，并通过综合火灾风险评估方法计算各工况总安全指数。结果表明:1号线站厅层和2号线站台层双点火灾为最不利火灾场景；1号线站台层和2号线站厅层双点火灾为相对安全火灾场景；火源功率的增大会增加地铁火灾危险性，但不同火源位置工况中的安全指数变化趋势相似；排烟模式开启前，1号线站厅层火灾会导致较大的火灾危险性；排烟模式开启后，地铁总安全指数显著上升且安全指数变化趋势改变，此时2号线站台层火灾会导致较大的火灾危险性。